Thermally stable rare earth dialkyl complexes supported by a novel bis(phosphinimine)pyrrole ligand.
نویسندگان
چکیده
A novel bis(phosphinimine)pyrrole based ligand (HL) and its synthesis are reported. Rare earth dialkyl complexes of the ligand, LLn(CH(2)SiMe(3))(2) (Ln = Er, Lu, Sc), have been prepared and found to exhibit high thermal stability in solution. The protio-ligand and dialkyl lanthanide complexes (Ln = Er, Lu) have been characterised by single crystal X-ray diffraction studies.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 26 شماره
صفحات -
تاریخ انتشار 2012